Scientists Characterize Shale Cap Rocks at Tiny Scales

Years of basic scientific research crosscutting multiple disciplines produces new information on the nanoscale complexities of shale.

The Science

Shale is a sedimentary rock made up of tiny grains of silica, clay and other minerals. Many types of rock have few physical or chemical differences in a particular chunk of that rock. Shale is different—it has a huge mix of physical and chemical features. These features include tiny nano-sized pores that connect to millimeter-scale fractures. This variation in scales affects how fluid moves through shale. Fluids move through these pores and fractures in unusual ways that are very difficult to measure and to model with traditional analytical and numerical tools. Researchers are now building new tools to examine, characterize, and simulate chemical and physical processes in shale. They are particularly interested in shale cap rock—layers of rock that are quite resistant to transport through them, making cap rock ideal for storing fluids in the layers of underlying rock that they seal.

The Impact

Scientists need a comprehensive understanding of how fluid moves through shale because this material has many potential roles in national economic security and the future of our environment. Shale has become an important source of natural gas and oil for U.S. consumers and industry, reducing dependence on foreign supplies. Shale is also the caprock or seal that prevents upward migration of carbon dioxide that has been captured at large emission sites or removed from the atmosphere and stored in the subsurface. This technology has a potential role in broader efforts to combat climate change. Shale can also potentially store hydrogen and other alternative fuels, helping make these fuels a viable alternative to petroleum. New tools and data are providing the information scientists need to understand how shale works in these and other applications.

Summary

The growing significance of shales and tight formations in energy production, clean energy fuels, and climate change mitigation is driving research to understand the physics of gas flow and barriers to flow within these systems. Shales are composed of highly heterogeneous physical and chemical features. Most nano-sized pores connect to millimeter-scale fractures, leading to multiscale transport. These nano-scale pores demonstrate non-classical flow behavior. As a result, classical computational fluid dynamics models do not accurately capture the physics involved. This complexity makes it essential for scientists to thoroughly explore geological formations capped by low-permeable shales. This exploration, or characterization, spans a wide range of physical and chemical porous media properties that describe the caprock, including pore size, distribution and geometry, fractures, connectivity, porosity, permeability, mineral composition, mechanical strength, and wettability. It also involves studying transport phenomena, thermodynamic properties, and methods to alter them, such as acid or base treatments, super-critical carbon dioxide injection, and mechanical alteration.

A team of researchers from Stanford University, the University of Wyoming, the University of Illinois Urbana Champaign, Stanford Linear Accelerator Laboratory, the University of Wisconsin, and the University of Southern California is working on a multidisciplinary approach to advancing the exploration of shale rock as a suitable geological seal for resource recovery and underground storage. Given that the pore space in shale rock is predominantly sub-micron, these studies focus on the micro and the nanoscale. The group’s work includes developing electron tomography capabilities for shale imaging, simulating methane adsorption and transport in shale, studying the effects of supercritical carbon dioxide on shale pore structures, and other related areas. The most recent published results involve simulating how methane flows through channels in shale at the nanoscale, and experimental work on how coupled mechanical and chemical processes serve to improve the sealing properties of shale.

Contact

Funding

This research was supported by the Center for Mechanistic Control of Unconventional Formations (CMC-UF), an Energy Frontier Research Center funded by the Department of Energy Office of Science.

Publications

Frouté, L., et al., Evaluation of Electron Tomography Capabilities for Shale Imaging. Microscopy and Microanalysis 29, 6 (2023). [DOI: 10.1093/micmic/ozad106]

Liu, L., Frouté, L., Kovscek, A.R., and Aryana, S., Scale translation yields insights into gas adsorption under nanoconfinement. Physics of Fluids 36, 7 (2024). [DOI: 10.1063/5.0212423]

Murugesu, M. P., et al., Coupled transport, reactivity, and mechanics in fractured shale caprocks. Water Resources Research 60,  1 (2024). [DOI: 10.1029/2023WR035482]

Noël, V., et. al., Dynamic development of geochemical reaction fronts during hydraulic stimulation of shale. Applied Geochemistry 148, 105542 (2023). [DOI: 10.1016/j.apgeochem.2022.105542]

Rustamov, N., Liu, L., and Aryana, S., Scalable simulation of coupled adsorption and transport of methane in confined complex porous media with density preconditioning. Gas Science and Engineering 119, 205131 (2023). [DOI: 10.1016/j.jgsce.2023.205131]

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Program: BES , CSGB

Performer: University , DOE Laboratory