Huge “Thermometer” Takes Temperatures of Tiny Samples

New spectroscopic technique measures heat in itty-bitty volumes that could reveal insights for electronics and energy technology.

Image courtesy of Oak Ridge National Laboratory

The Science

The tool is a 13-foot-tall electron microscope nicknamed a “quantum spectrometer.” Scientists took advantage of spectroscopic techniques that have high spatial resolution when coupled with a narrow probe. They measured the local temperature of a material from a small volume. The width of the volume was about a billionth of a meter wide. That is approximately 100,000 times thinner than a human hair.

The Impact

Useful, yet unusual. At the nanoscale, materials don’t behave as they usually do (that is, when they are in larger quantities). For example, a block of gold is inert, but gold at the nanoscale is a catalyst. This discovery promises to improve our ability to understand physical and chemical behaviors that arise at the nanoscale. This tool could map atomic-scale vibrations due to heat. The vibrations affect microelectronic devices, semiconducting materials, and other technologies.

Summary

Atoms are always shaking. The higher the temperature, the more the atoms shake. In this study, scientists used a specialized instrument made by the Nion Company that produces images with both high spatial resolution and great spectral detail. The instrument is called HERMES, short for high-energy-resolution, monochromated, electron-energy-loss-spectroscopy scanning transmission electron microscope.

Scientists used HERMES to measure the temperature of semiconducting hexagonal boron nitride. They observed atomic vibrations that correspond to heat in the material. They characterized nanoscale environments at room temperature to about 1300 degrees Celsius (2372 degrees Fahrenheit) using a newly developed Protochips heating device. Unlike typical thermometers, the HERMES “thermometer” does not require prior temperature calibration. The experimenter need only know the energy and intensity of an atomic vibration in a material—both of which are measured during the experiment.

This experiment used electron energy gain and loss spectroscopies to study atomic vibrations. In electron energy loss spectroscopy, the microscope’s electron beam loses energy as it passes through the sample. In contrast, in energy gain spectroscopy, the electrons gain energy from interacting with the sample.The scientists calculated the ratio between energy gain and loss to derive the temperature of the tiny portion of the sample through which the electrons traveled. This gives the “thermometer” nanoscale resolution. It may now be possible to characterize local temperature during phase transitions in materials. HERMES could be useful for studying devices working across a wide range of temperatures, from electronics operating under ambient conditions to vehicle catalysts performing at over 300 degrees Celsius (around 570 degrees Fahrenheit).

Contact

Juan Carlos Idrobo
Center for Nanophase Materials Sciences, Oak Ridge National Laboratory
[email protected]

Andrew R. Lupini
Materials Science and Technology Division, Oak Ridge National Laboratory
[email protected]

Funding

This research was supported by the Center for Nanophase Materials Sciences, a Department of Energy (DOE) Office of Science user facility at Oak Ridge National Laboratory (ORNL), and by the Materials Sciences and Engineering Division of DOE’s Office of Science, Basic Energy Sciences (BES). This research used resources of the National Energy Research Scientific Computing Center, a DOE Office of Science user facility at Lawrence Berkeley National Laboratory, and instrumentation within ORNL’s Materials Characterization Core. This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by the National Science Foundation. Theoretical work at Vanderbilt University was supported by a DOE BES award and by the McMinn Endowment.

Publications

J.C. Idrobo, A.R. Lupini, T. Feng, R.R. Unocic, F.S. Walden, D.S. Gardiner, T.C. Lovejoy, N. Dellby, S.T. Pantelides, and O.L. Krivanek, “Temperature measurement by a nanoscale electron probe using energy gain and loss spectroscopy.” Physical Review Letters 120, 095901 (2018). [DOI 10.1103/PhysRevLett.120.095901]